Light provides pull for future nanocatalyst measurement

( Nanowerk News) Rice University nanophotonics researcher Isabell Thomann uses lasers, light-activated materials and light-measuring nanoscale tips to push the boundaries of experimental nanoscience, but light is providing the pull in her latest study.

In a new paper in the American Chemical Society journal Nano Letters ( “Photoinduced Force Mapping of Plasmonic Nanostructures”), Thomann and colleagues, including postdoctoral fellow Thejaswi Tumkur and graduate student Xiao Yang, combine experiment and theory to test a new technique called “photo-induced force microscopy,” which probes the optical properties of nanomaterials by measuring the physical force imparted by light.

An illustration (left) depicts the technique known as “photo-induced force microscopy,” and the images at right show how closely the experimental and theoretical findings match in a recent investigation of the technique at Rice University. H gas l gas unterschied (Illustration: Chloe Doiron/Rice University. Electricity deregulation (© American Chemical Society)

Thomann’s primary research centers on using nanoparticles and sunlight to reduce the carbon footprint of power plants. Electricity sources uk The work crosses boundaries of chemistry, optics, electrical engineering, energy and the environment, but a major focus is photocatalysis, a class of processes in which light interacts with high-tech materials to drive chemical reactions.

“Many experiments nowadays are done under high vacuum, but I want to run the reactor in my lab under more realistic conditions — normal temperature, normal pressure, in the presence of water — that will apply to capturing sunlight for photocatalysis,” said Thomann, an assistant professor of electrical and computer engineering, of materials science and nanoengineering and of chemistry at Rice.

Thomann has been working to develop new tools for measuring nanomaterials since arriving at Rice in 2012. Electricity cost per watt She and her team are developing an ultrafast laser spectroscopy system that can read the optical signatures of short-lived chemical processes that are relevant to artificial photosynthesis.

“In a chemical reaction, there are reactants, which are the chemical inputs, and there are products, which are the outputs,” Thomann said. Gas density at stp “Almost all reactions driven by light involve multiple steps where light is converted to quantum particulates such as electrons or phonons that need to be transported to surfaces to drive chemical reactions. Electricity quiz ks2 It is very helpful to know exactly what these are, when they are made and in what quantity, particularly if you are optimizing a process for industrial use.”

Thomann’s group designs light-activated nanoparticles that can capture energy from sunlight and use it to initiate chemical reactions. Electricity questions grade 9 The nanocatalysts, which can be tiny rods or discs of metal or other materials, interact with light due in part to their shapes and how closely they are spaced together. 4 gas planets Thomann said that while engineers make every effort to produce uniform particles, small imperfections still exist and can have significant consequences on performance.

These images show the measured optical forces for an array of plasmonic gold disc pairs known as dimers that were probed by an atomic force microscopy tip. Arkla gas phone number The map reveals slight differences caused by minute imperfections in the dimers. Electricity deregulation in california (Image: Thomann Group/Rice University. Gas x and pregnancy © American Chemical Society) (click on image to enlarge)

“Photocatalysts are often heterogeneous, which means they are not all exactly alike, and we need better tools for examining them with high spatial resolution in order to see these small differences,” she said. 8 gases “We also need to follow the reaction processes with high temporal resolution, and we want to do all of this with much better spatial resolution than can be achieved with a normal optical microscope.”

In the photon-induced force microscopy experiments, Thomann’s team used a tiny tip from an atomic force microscope (AFM) to enhance the spatial resolution of measurements taken from gold nanorods and nanodiscs on glass surfaces. Electricity font generator The rods and discs, which are smaller than the wavelength of light used to measure them, would normally be blurry in an optical microscope due to a physical property called the diffraction limit. Hair electricity song To better resolve the nanoparticles, and the electromagnetic interactions between them, Thomann’s group shines light at the particles and uses an AFM tip to probe how these nanoparticles act as optical nanoantennas and concentrate the light.

“If we were trying to measure the reflected light, it would be very difficult because there are only a few scattered photons against a very busy background where light is bouncing all over the place, especially if these measurements were carried out in a liquid environment,” Thomann said. Z gas el salvador numero de telefono “But we are instead measuring the force exerted on the AFM tip, the slight pull on the tip when the optical nanoantennas are illuminated by light. Electricity was invented in what year It turns out that measuring the force is a much more sensitive technique than trying to collect the few photons scattered off the tip.”

Thomann said the study provides theoretical understanding of how photo-induced force microscopy works and lays the groundwork for future studies of more complex photocatalyst materials her team hopes to create in the future. Electricity icon She credited her group’s improved understanding of the force-measuring technique to months of hard work by co-author Xiao Yang, a Rice graduate student in the group of theoretical physicist and study co-author Peter Nordlander.

Yang said the most difficult part of coming up with an explanation of the team’s experimental results was creating a solvable computational model that accurately described the real-world physics. Electricity 2pm live For example, including the entire tip in the model made the mathematics impractical.

“I did try, at first, but it turned out it was impossible,” Yang said. Gas utility boston “It would have taken an infinite time to reach convergence of the simulations.”

Yang eventually hit upon an idea — including just a portion of the tip in the model — that made the calculations both feasible and accurate. Gas density conversion Thomann said this was just one example of Yang’s tenacity in finding a workable solution.

In a new paper in the American Chemical Society journal Nano Letters, Thomann and colleagues, including postdoctoral fellow Thejaswi Tumkur and graduate student Xiao Yang, combine experiment and theory to test a new technique called “photo-induced force microscopy,” which probes the optical properties of nanomaterials by measuring the physical force imparted by light.

Thomann’s primary research centers on using nanoparticles and sunlight to reduce the carbon footprint of power plants. Gas and supply locations The work crosses boundaries of chemistry, optics, electrical engineering, energy and the environment, but a major focus is photocatalysis, a class of processes in which light interacts with high-tech materials to drive chemical reactions.

“Many experiments nowadays are done under high vacuum, but I want to run the reactor in my lab under more realistic conditions—normal temperature, normal pressure, in the presence of water—that will apply to capturing sunlight for photocatalysis,” said Thomann, an assistant professor of electrical and computer engineering, of materials science and nanoengineering and of chemistry at Rice.

Thomann has been working to develop new tools for measuring nanomaterials since arriving at Rice in 2012. Gas exchange in the lungs is facilitated by She and her team are developing an ultrafast laser spectroscopy system that can read the optical signatures of short-lived chemical processes that are relevant to artificial photosynthesis.

“In a chemical reaction, there are reactants, which are the chemical inputs, and there are products, which are the outputs,” Thomann said. Gas weed “Almost all reactions driven by light involve multiple steps where light is converted to quantum particulates such as electrons or phonons that need to be transported to surfaces to drive chemical reactions. Gas and electric nyc It is very helpful to know exactly what these are, when they are made and in what quantity, particularly if you are optimizing a process for industrial use.”

Thomann’s group designs light-activated nanoparticles that can capture energy from sunlight and use it to initiate chemical reactions. Gas finder app The nanocatalysts, which can be tiny rods or discs of metal or other materials, interact with light due in part to their shapes and how closely they are spaced together. Electricity vs magnetism Thomann said that while engineers make every effort to produce uniform particles, small imperfections still exist and can have significant consequences on performance.

In the photon-induced force microscopy experiments, Thomann’s team used a tiny tip from an atomic force microscope (AFM) to enhance the spatial resolution of measurements taken from gold nanorods and nanodiscs on glass surfaces. Gas guzzler tax The rods and discs, which are smaller than the wavelength of light used to measure them, would normally be blurry in an optical microscope due to a physical property called the diffraction limit. Electricity in homes To better resolve the nanoparticles, and the electromagnetic interactions between them, Thomann’s group shines light at the particles and uses an AFM tip to probe how these nanoparticles act as optical nanoantennas and concentrate the light.

“If we were trying to measure the reflected light, it would be very difficult because there are only a few scattered photons against a very busy background where light is bouncing all over the place, especially if these measurements were carried out in a liquid environment,” Thomann said. Electricity games online free “But we are instead measuring the force exerted on the AFM tip, the slight pull on the tip when the optical nanoantennas are illuminated by light. Electricity water analogy It turns out that measuring the force is a much more sensitive technique than trying to collect the few photons scattered off the tip.”

Thomann said the study provides theoretical understanding of how photo-induced force microscopy works and lays the groundwork for future studies of more complex photocatalyst materials her team hopes to create in the future. Electricity 101 She credited her group’s improved understanding of the force-measuring technique to months of hard work by co-author Xiao Yang, a Rice graduate student in the group of theoretical physicist and study co-author Peter Nordlander.

Yang said the most difficult part of coming up with an explanation of the team’s experimental results was creating a solvable computational model that accurately described the real-world physics. Electricity meme For example, including the entire tip in the model made the mathematics impractical.

“I did try, at first, but it turned out it was impossible,” Yang said. Gas x side effects liver “It would have taken an infinite time to reach convergence of the simulations.”

Yang eventually hit upon an idea—including just a portion of the tip in the model—that made the calculations both feasible and accurate. Ag gaston funeral home birmingham al Thomann said this was just one example of Yang’s tenacity in finding a workable solution.